Both play slight different role in routing. MVC is server side while AngularJS is client side performing routing.
There is routing module ngRoute which is supported in AngularJS with single page application. This define rules to render URL with routing. It get the URL from the users request, then routing engine render the view of url based on rules. AngularJS appends # in url to redirect specified url by the help or $location service. For example if you use http://localhost/users then routing engine will render it with http://localhost/#/users